Ordered Nanoporous Alumina Membranes Formed in Oxalic/Phosphoric Acid Using Hard Anodization

ordered nanoporous alumina membranes formed in oxalic/phosphoric acid using hard anodization

highly self-ordered alumina nanopore arrays were fabricated using hard anodization technique in different mixtures of oxalic/phosphoric acid. the phosphoric acid concentration was varied from 0.05 to 0.3 m while the oxalic acid concentration was changed between 0.3 and 0.4 m. the self ordered nanoporous arrays were obtained in anodization voltage changing from 130 to 200 v. the interpore distan...

Self-ordered anodic aluminum oxide formed by H2SO4 hard anodization.

The self-ordering of nanoporous anodic aluminum oxide (AAO) in the course of the hard anodization (HA) of aluminum in sulfuric acid (H2SO4) solutions at anodization voltages ranging from 27 to 80 V was investigated. Direct H2SO4-HA yielded AAOs with hexagonal pore arrays having interpore distances D(int) ranging from 72 to 145 nm. However, the AAOs were mechanically unstable and cracks formed a...

Structural tuning of photoluminescence in nanoporous anodic alumina by hard anodization in oxalic and malonic acids

We report on an exhaustive and systematic study about the photoluminescent properties of nanoporous anodic alumina membranes fabricated by the one-step anodization process under hard conditions in oxalic and malonic acids. This optical property is analysed as a function of several parameters (i.e. hard anodization voltage, pore diameter, membrane thickness, annealing temperature and acid electr...

Fabrication of Self-Ordered Alumina Films with Large Interpore Distance by Janus Anodization in Citric Acid

Self-organized porous anodic alumina (PAA) formed by electrochemical anodization have become a fundamental tool to develop various functional nanomaterials. However, it is still a great challenge to break the interpore distance (Dint) limit (500 nm) by using current anodization technologies of mild anodization (MA) and hard anodization (HA). Here, we reported a new anodization mode named "Janus...

Monitoring Transport Across Modified Nanoporous Alumina Membranes

This paper describes the use of several characterization methods to examinealumina nanotubule membranes that have been modified with specific silanes. The functionof these silanes is to alter the transport properties through the membrane by changing thelocal environment inside the alumina nanotube. The presence of alkyl groups, either long(C18) or short and branched (isopropyl) hydrocarbon chai...

Supporting Information Structural Tuning of Photoluminescence in Nanoporous Anodic Alumina by Hard Anodization in Oxalic and Malonic Acids